| Improving Effluent
Quality
As discharge limits continue to tighten or as
enforcement of existing limits increases many of our customers and
others have been forced to improve their average effluent quality.
In most cases this has been accomplished simply by improving the
operation of the existing system. Often paying a little more
attention to the waste treatment system, narrowing the pH band
acceptable for discharge, and better scheduling of system
maintenance and calibration of all probes and meters is all that
is necessary.
In some cases however the limits have become so
strict that it has been necessary to supplement the precipitation
of heavy metals as hydroxides with the use of sulfide
precipitation or post treatment such as ion exchange or
absorption. The use of various sulfide compounds for precipitation
of heavy metals is quite common. Metal Sulfides are generally less
soluble than similar metal hydroxides. In most cases the addition
of 5 to 50 PPM of sulfide to a metal hydroxide precipitation
system will dramatically improve the final effluent quality. The
use of sulfide usually will also improve the removal of chelated
or completed metal ions as well. Sulfide chemistries work well for
common chelating agents such as NTA, EDTA, and Gluconates and
complexing agents such as ammonia
Treatment Products can provide chemical feed
packages and controls to prepare and feed the Sulfide solution and
any other necessary reagents. Typically the sulfide feed pump is
controlled such that it strokes in tandem with the caustic feed
pump and the sulfide is fed proportionately to the caustic added.
One disadvantage of using a sulfide based
chemistry is the potential for forming odorous toxic hydrogen
sulfide gas when either the sludge or the effluent is acidified.
However there are many ways to reduce the risk of this occurring.
In many situations the advantages of this chemistry far outweigh
the disadvantages
Polishing selective ion exchange or absorption
can also be an effective methods of removing trace metals. In
metals removal waste treatment and recovery applications with low
metals effluent limits conventional precipitation systems may be
unable to continuously and consistently achieve compliance. The
effluent from a conventional precipitation system can be further
treated by ion exchange or selective absorbents to consistently
reduce the total metals to as low as 20 PPB with a properly
selected ion exchange resin or absorbents. With properly selected
media even chelated or complexed metals can be removed. Typically
the media is chosen based on its ability to selectively remove the
contaminants (metals, or metal complexes) from the waste stream
while allowing the background salts to pass through. Treatment
Products provides units with both regenerable and disposable
media. Generally regenerable units are used for high flow or high
inlet contaminant concentration applications, and disposable units
are used for low flow or low inlet contaminant concentration
applications.
Treatment Products can assist you with any or
all phases of improving your effluent discharge quality. We can
assist you in optimizing the performance of your existing system
and recommend and supply any necessary post treatment equipment.
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